Some 15 years ago when I was slinging often for a period, I could do 100-meter throws on a fairly regular basis. I was throwing across an old sand/gravel pit which was about 100 metres across. (At least according to the guy who owned the place) The pit had a seemingly endless supply of well-rounded stones of suitable size, so I had unlimited access to free ammo.
If I threw 10 stones, 6-7 of them landed on the ground outside the pit on the other side, with a spread of maybe 3 metres. (I doubt I could do that today, though - at least not without lots of practice first.)
I also had fun setting up balloons at distances of 15-30 metres and banging them with stones from the sling. (Sometimes I would draw faces on the balloons, too - OK, it might be childish, but it
was a lot of fun!!!)
Lasse C