Dale
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P.W._Smith,
The only solid information I have for you concerns sling ammunition. Archaeological digs in Israel continually turn up sling stones that actually are stones (often shaped by tools) or that are made of baked clay. Real stones are more durable; clay is more readily found. I do not know if the Israelites (or Philistines or others, for that matter) used lead or other metals.
I have no information, but do have some speculations, concerning the slings themselves. Throughout the world, slings have been made from materials at hand: leather, animal hair (wool or similar), or plant fibers (grasses, jute, hemp, dogbane, or similar). I would expect the slings wielded by the Benjaminites (mentioned in Judges) or by David (the books of Samuel) to have been made from wool or goathair, possibly with leather for the pouch (or to cover the straps of a split pouch, as is done in Mallorca today).
Again, these are my own speculations about the slings. If you need definitive information, you may need to find someone who lives in the Middle East and who knows of a good museum. I have had no luck searching on the web.
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